The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.     

Geological interpretation of a deep seismic‐reflection transect across the boundary between the Delamerian and Lachlan Orogens,in the vicinity of the Grampians,western Victoria

A deep seismic‐reflection transect in western Victoria was designed to provide insights into the structural relationship between the Lachlan and the Delamerian Orogens. Three seismic lines were acquired to provide images of the subsurface from west of the Grampians Range to east of the Stawell‐Ararat Fault Zone. The boundary between the Delamerian and Lachlan Orogens is now generally considered to be the Moyston Fault. In the vicinity of the seismic survey, this fault is intruded by a near‐surface granite, but at depth the fault dips to the east, confirming recent field mapping. East of the Moyston Fault, the uppermost crust is very weakly reflective, consisting of short, non‐continuous, west‐dipping reflections. These weak reflections represent rocks of the Lachlan Orogen and are typical of the reflective character seen on other seismic images from elsewhere in the Lachlan Orogen. Within the Lachlan Orogen, the Pleasant Creek Fault is also east dipping and approximately parallel to the Moyston Fault in the plane of the seismic section. Rocks of the Delamerian Orogen in the vicinity of the seismic line occur below surficial cover to the west of the Moyston Fault. Generally, the upper crust is only weakly reflective, but subhorizontal reflections at shallow depths (up to 3 km) represent the Grampians Group. The Escondida Fault appears to stop below the Grampians Group, and has an apparent gentle dip to the east. Farther east, the Golton and Mehuse Faults are also east dipping. The middle to lower crust below the Delamerian Orogen is strongly reflective, with several major antiformal structures in the middle crust. The Moho is a slightly undulating horizon at the base of the highly reflective middle to lower crust at 11–12 s TWT (approximately 35 km depth). Tectonically, the western margin of the Lachlan Orogen has been thrust over the Delamerian Orogen for a distance of at least 25 km, and possibly over 40 km.     

Water chemistry and sedimentological observations in littlefield lake,michigan: Implications for lacustrine marl deposition

A combination of both water chemistry and sedimentological information was used to investigate the carbonate-producing mechanism in Littlefield Lake, a small lake located in Isabella County, central Michigan. Data on temperature, dissolved oxygen, pH, calcium carbonate (CaCO₃) saturation, alkalinity, calcium, and magnesium were obtained on a monthly basis over a 13-month period, with each parameter determined at 1m intervals over a depth range of 20m. The loss of dissolved carbon dioxide (CO₂) from warm surface waters during direct degassing, and to a lesser extent during photosynthetic uptake by lacustrine macrophytes and phytoplankton during the summer, results in massive precipitation of the low-magnesium calcite which predominates in all Littlefield Lake sedimentary facies However, despite the fact that carbonate precipitation in this rather typical temperate-region marl lake is directly related to, and may be driven by, seasonal variation in these physiochemical parameters, most calcite forms as encrustations around cyanophytic and chlorophytic macrophytes. Such relationships demonstrate that carbonate precipitation in marl lakes may result from complex interactions between both biochemical and physiochemical processes. As such, marl formation in this, and probably many other calcareous lake systems, can not be simply ascribed to one or the other of these two general mechanisms.     

OCCURRENCE OF VOLATILE ORGANIC CHEMICALS IN NEBRASKA GROUND WATER

Abstract. This report summarizes results of monitoring programs for volatile synthetic organic chemicals (VOCs) in Nebraska's private and public water-supply wells conducted by two State agencies. Of 97 community water-supply systems sampled as of June 1984, 16.5 percent (16 systems) showed quantifiable levels of at least one VOC. Detectable amounts of one or more VOCs were measured in samples from 15.9 percent (10) of 63 private wells sampled in 1982. These percentages are consistent with results of other State and national surveys.     

Contrasting climatic histories for the Snake River Plain, Idaho, resulting from multiple thermal maxima

Ten sites near the Snake River Plain have consistent differences in their climatic histories. Sites at low elevation reflect the “early Holocene xerothermic” of the Pacific Northwest, whereas most climatic chronologies at high elevation indicate maximum warmth or aridity somewhat later, ca. 6000 yr ago. This elevational contrast in climatic histories is duplicated at three sites from the central Snake River Plain. For sites in such close proximity, the different chronologies cannot be explained by changes in atmospheric circulation during the late Quaternary. Rather, the differences are best explained by the autecology of the plants involved and the changing seasonal climate. The seasonal climatic sequence predicted by multiple thermal maxima explains the high- and low-elevation chronologies. During the early Holocene, maximum insolation and intensified summer drought in July forced low-elevation vegetation upward. However, moisture was not a limiting factor at high elevation, where vegetation moved upward in response to increased length of growing season coincident with maximum September insolation 6000 yr ago.     

Spatial and temporal distribution of diatoms in sediments of Lake Malawi,Central Africa,and ecological implications

Lake Malawi lies in a major rift valley in Central Africa that is some 700 m deep and 550 km long. A total of 242 cores and 111 grab samples were recovered between 1984 and 1989 and form the data base for a study of diatom distribution in this lake basin. The sediments consist of homogeneous diatomites, pelagic diatomaceous muds, varved diatomite-mud couplets, turbidites, littoral sand sheets and extensive deposits of ferro-manganous nodules.Fossil diatoms show major temporal and regional contrasts between the southern, central and northern areas of the lake. A wide variety of Aulacoseira species occur in the southern lake sediments. To the north, the Nkhotakota region is generally characterised by Stephanodiscus and Aulacoseira, with occasional diatomite laminae composed of Aulacoseira or Nitzschia. The central parts of the lake show the greatest variation, with Stephanodiscus, Nitzschia and Aulacoseira all being prominent. The northern region is dominated by Aulacoseira nyassensis throughout most core sequences.Variability in these assemblages appears to be controlled by Si:P ratios, Si concentrations, turbulence and light penetration. These factors themselves are influenced by differences in the depth and duration of lake mixing due to variations in wind strength, seiches and bottom topography among different regions of the lake and from lakewide circulation patterns.     

Behavior of Titan's atmosphere during a total eclipse

The edge-on presentation of Saturn's rings and satellites system has provided a rare opportunity to observe total eclipses of Titan. During its emersion from the Saturnian shadow (1980, June 28), Titan has been observed simultaneously in the visible and the infrared ranges (6000–9000 Å, 11.8 μm and 20 μm). No change has been recorded in these three spectral ranges. Our observations tend to support the thick-atmosphere model, which has been shown to be valid by Voyager a few months later.     

The 1.95-2.50 μm Spectrum of J6 Himalia

The reflectance spectrum of Jupiter's sixth satellite, Himalia, is featureless in the wavelength region 1.95-2.50 μm as seen at a spectral resolution of 0.005 μm, with no absorptions deeper than a few percent. From model calculations we establish an upper limit of 10% by weight of H₂O (30-μm grains) mixed intimately in the soil of Himalia, or alternatively 0.3% of the surface covered by exposures of H₂O ice spatially segregated from the darker soil. For CH₄ and CO₂ ices the upper limits in spatially segregated models are both 0.3%.     

An evaluation of hemolymph cholinesterase activities in the tropical scallop,Euvola (Pecten) ziczac,for the rapid assessment of pesticide exposure

The use of sequential measurements of hemolymph cholinesterase activities as a non-invasive biomarker of seasonal organophosphate/carbamate exposure was investigated for the tropical scallop, Euvola (Pecten) ziczac. Overall activities of both acetylcholinesterase and butyrylcholinesterase were relatively high compared to studies with bivalve tissues. Acute in vivo experiments showed inhibition of hemolymph acetylcholinesterase activity at concentrations of the organophosphate insecticide chlorpyrifos of 0.1, 1 and 10 ng l(-1). Monthly sampling of hemolymph from scallops at two sites in Bermuda over a 15 month period showed seasonal acetylcholinesterase and butyrylcholinesterase inhibition. Direct and indirect evidence suggests that this inhibition did not relate to biochemical or physiological changes associated with gonad maturation and spawning, but rather reflected diffuse contamination of the marine environment by cholinesterase inhibitors or increased bioavailability of such inhibitors at these times. Repetitive sampling of scallop hemolymph for cholinesterase activities represents a rapid, sensitive and non-invasive method for assessing seasonal, sublethal pesticide exposure in these commercially important bivalves and suggests a wider use in marine pollution monitoring.     

Ammonite biostratigraphy of the Albian in the Kirchrode II borehole, Hannover, Germany

The ammonite biostratigraphy of the 279.35 m of sediments of mid-Late Albian–Early Albian age traversed by the Kirchrode II (1/94) boring is described. The borehole was drilled in the Hermann-Löns Park, Kirchrode (Hannover), northwest Germany, in the central region of the Lower Saxony sedimentary basin. The core commenced within the Kirchrode Mergel Member of the Gault Formation in sediments of Callihoplites auritus Subzone age and showed a Late Albian ammonite zonal succession similar to that previously described by Wiedmann and Owen from the lower part of the nearby Kirchrode I (1/91) core, with which it is correlated. The thick underlying clay sediments of the Minimus Ton Member (Middle Albian–late Early Albian) provided a relatively sparse ammonite fauna. In the Middle Albian part of the sediment succession, several hiatuses are present and only sediments of the lower Euhoplites loricatus Zone (Anahoplites intermedius Subzone) and the Hoplites dentatus Zone (Hoplites spathi Subzone) have been identified. This is followed downward by a thick sedimentary succession through the upper part of the Early Albian Douvilleiceras mammillatum Superzone (Otohoplites auritiformis Zone). Earlier mammillatum and perhaps latest Leymeriella tardefurcata Zone portions of the core straddling the Minimus Ton/Schwicheldt Ton boundary, did not yield ammonites. The underlying sediments at the top of the Schwicheldt Ton Member, consist of dark clays and mudstones with a good representation of the Leymeriella (Neoleymeriella) regularis Subzone and the uppermost part of the Leymeriella acuticostata Subzone (Leymeriella tardefurcata Zone). Of particular importance is the succession through the sediments of the L. (N.) regularis Subzone, hitherto poorly known in north Germany. A brief comparison and correlation is made with other surface and borehole sections in northern Germany and elsewhere. The Boreal and more cosmopolitan Tethyan elements of the fauna are indicated and discussed. An appendix of ammonites obtained from the Mittellandkanal section at Misburg of latest Albian, Arraphoceras (Praeschloenbachia) briacensis Subzone age, completes the study.